3-(4-Fluoro­phenyl­sulfin­yl)-2,5-dimethyl-1-benzofuran

نویسندگان

  • Hong Dae Choi
  • Pil Ja Seo
  • Byeng Wha Son
  • Uk Lee
چکیده

In the title compound, C(16)H(13)FO(2)S, the O atom and the 4-fluoro-phenyl group of the 4-fluoro-phenyl-sulfinyl substituent are located on opposite sides of the plane through the benzofuran fragment; the 4-fluoro-phenyl ring is nearly perpendicular to this plane, making a dihedral angle of 87.41 (3). The crystal structure exhibits a weak inter-molecular C-H⋯O hydrogen bond.

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منابع مشابه

3-(4-Fluoro­phenyl­sulfin­yl)-5-iodo-2,7-dimethyl-1-benzofuran

In the title compound, C(16)H(12)FlO(2)S, the 4-fluoro-phenyl ring makes a dihedral angle of 80.21 (6)° with the mean plane of the benzofuran fragment. In the crystal, mol-ecules are linked through weak inter-molecular C-H⋯O hydrogen bonds. The crystal structure also exhibits an inter-molecular I⋯F contact [3.423 (2) Å].

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5-Bromo-3-(4-fluoro­phenyl­sulfin­yl)-2,7-dimethyl-1-benzofuran

In the title compound, C(16)H(12)BrFO(2)S, the 4-fluoro-phenyl ring makes a dihedral angle of 83.29 (5)° with the mean plane of the benzofuran fragment. In the crystal, mol-ecules are linked by weak inter-molecular C-H⋯O hydrogen bonds.

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2,5-Dimethyl-3-phenyl­sulfonyl-1-benzofuran

The title compound, C(16)H(14)O(3)S, was prepared by the oxidation of 2,5-dimethyl-3-phenyl-sulfanyl-1-benzofuran with 3-chloro-peroxy-benzoic acid. The phenyl ring makes a dihedral angle of 76.98 (9)° with the plane of the benzofuran fragment. The crystal structure is stabilized by π-π inter-actions between furan and benzene rings of neighbouring mol-ecules [centroid-centroid distance = 3.775 ...

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3-(4-Bromo­phenyl­sulfin­yl)-2,5-dimethyl-1-benzofuran

In the title compound, C(16)H(13)BrO(2)S, the 4-bromo-phenyl ring makes a dihedral angle of 87.87 (6)° with the mean plane of the benzofuran fragment. In the crystal, mol-ecules are linked by a weak π-π inter-action between the 4-bromo-phenyl rings [centroid-to-centroid distance = 3.907 (3) Å, inter-planar distance = 3.528 (3) Å and slippage = 1.679 (3) Å].

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3-(3-Fluoro­phenyl­sulfin­yl)-5-iodo-2,7-dimethyl-1-benzofuran

In the title compound, C(16)H(12)FIO(2)S, the 3-fluoro-phenyl ring makes a dihedral angle of 76.47 (6)° with the mean plane [r.m.s. deviation = 0.013 (2) Å] of the benzofuran fragment. In the crystal, mol-ecules are linked by weak C-H⋯O hydrogen bonds,forming chains along the b-axis direction, and an I⋯O contact [3.204 (2) Å]. The crystal structure also exhibits slipped π-π inter-actions betwee...

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عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010