Ab initio modeling of the elementary reactions during thermal decomposition of polysulfides
نویسندگان
چکیده
Introduction Polysulfides play a critical role in the optimization of many chemical processes. Dimethyl disulfide (DMDS), for example, is used as coke inhibiting additive in steam cracking furnaces and can also be used as photolytic initiator during free radical polymerization.[1, 2] Also tetrasulfides are frequently used in chemistry, mostly as inhibitors during polymerization reactions. Despite the industrial significance of polysulfides, experimental and theoretical studies concerning their reaction behavior are scarce.
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