Hydrogenation of Unsaturated Fatty Esters With Copper- Chromite Catalyst: Kinetics, Mechanism and Isomerization1
نویسنده
چکیده
II S, stearate; M, mOlloene; D, diene; T, trien€; CD, conjugated {Hene; eDT, conjugated diene-triene. Copper chl'omite 9.12.15 8.9 22.9 33,S 4,6 31.6 17 Nickel 9,12,15 0,9 40,S 21.1 0,5 20 Copper chromite 5,9,12 O,S 27.3 39.4 30,2 0,9 1.4 18 Copper chromite 3.9,12 lOJ 22.3 69,4 6,7 18 D T CD CDT Composition, % Position of double bonds in tl'ienes Analyses of Products Formed During :Hydrogenutioll of :Methyl Linolenate and Its Isomers
منابع مشابه
Selective Hydrogenation With Copper Catalysts: II. Kinetics
To explain the unusually high selectivity of copper catalysts toward linolenate, model compounds were hydrogenated (150 C and atmospheric pressure) and the reaction products analyzed. Products varied depending upon location of the double bonds. Monoenes were not reduced by copper chromite except when the double bond was next to a carboxyl group. Dienes with isolated double bonds also were not r...
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Samples taken during deuteration of methyl linoleate with the title catalysts were separated into saturate, monoene and diene fractions. Monoenes were further separated into cis and trans fractions. A comparison of the double bond distribution in monoenes with those from hydrogenation of alkaliconjugated !inoleate indicated that up to 59% of the !inoleate was reduced through a conjugated interm...
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