Efficient detection of polycyclic aromatic hydrocarbons and polychlorinated biphenyls via three-component energy transfer.
نویسندگان
چکیده
Reported herein is the detection of highly toxic polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) via proximity-induced non-covalent energy transfer. This energy transfer occurs in the cavity of γ-cyclodextrin, and is efficient even with the most toxic PAHs and least fluorescent PCBs. The low limits of detection and potential for selective detection using array-based systems, combined with the straightforward experimental setup, make this new detection method particularly promising.
منابع مشابه
Microscale detection of polychlorinated biphenyls using two-step laser mass spectrometry
Microprobe two-step laser desorption/laser ionization mass spectrometry ( LMS) is used as a new analytical technique for the detection of polychlorinated biphenyls (PCBs). Three standard Aroclor solutions (Aroclor 1232, 1242, and 1262) and three samples of activated carbon spiked with Aroclor 1242 are examined. All the PCBs present in the Aroclor solutions are clearly identified using LMS. The ...
متن کاملPolybrominated Diphenyl Ethers Furans Polychlorinated Biphenyls Heavy Metals Polycyclic Aromatic Hydrocarbons Organophosphate Pesticides Trihalomethanes Organochlorine Pesticides Volatile Organic Compounds Similar Toxicological Properties and/or Effects Allergic Contact Sensitizers Hepatotoxicants Genetic Carcinogens Immunotoxicants Nongenetic Carcinogens Nephrotoxicants Cardiovascular Toxicants
متن کامل
Occurrence, Fate and Treatment Methods of Polycyclic Aromatic Hydrocarbons, Polychlorinated Biphenyls, Dioxins and Furans: A Mini Review
Polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), dioxins and furans are persistent organic pollutants with well-known toxicity and carcinogenic activity. These organic pollutants have the tendency to bioaccumulate, present little or no biodegradation and subsequently, could cause a menace to the ecosystems and human health. This review discusses the occurrence, fate an...
متن کاملPolycyclic aromatic hydrocarbons, polychlorinated biphenyls, and chlorinated pesticides in background air in central Europe – investigating parameters affecting wet scavenging of polycyclic aromatic hydrocarbons
Concentrations of polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), and chlorinated pesticides (CPs) were measured in air and precipitation at a background site in central Europe. ∑ PAH concentrations in air and rainwater ranged from 0.7 to 327.9 ng m and below limit of quantification (< LOQ) to 2.1× 10 ng L. The concentrations of PCBs and CPs in rainwater were < LOQ. ∑...
متن کاملIn Situ Stabilization of Persistent Organic Contaminants in Marine Sediments
Microprobe two-step laser desorption/laser ionization mass spectrometry (μLMS) is used as a new analytical technique for the detection of polychlorinated biphenyls (PCBs). Three standard Aroclor solutions (Aroclor 1232, 1242, and 1262) and three samples of activated carbon spiked with Aroclor 1242 are examined. All the PCBs present in the Aroclor solutions are clearly identified using μLMS. The...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 49 42 شماره
صفحات -
تاریخ انتشار 2013