An indicator displacement system for fluorescent detection of phosphate oxyanions under physiological conditions

نویسندگان

  • Roger G. Hanshaw
  • Sarah M. Hilkert
  • Hua Jiang
  • Bradley D. Smith
چکیده

A fluorogenic chemosensing system is described and shown to selectively detect pyrophosphate under physiological conditions. In the best case, pyrophosphate and hydrogen phosphate are capable of displacing a fluorescent coumarin-derived indicator from a bis Zn-dipicolylamine coordination compound with association constants of 10 and 10M , respectively. 2004 Elsevier Ltd. All rights reserved.

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تاریخ انتشار 2004