catena-Poly[(S)-2-methylpiperazine-1,4-diium [[trichloridobismuthate(III)]-di-μ-chlorido]]
نویسنده
چکیده
In the crystal structure of the title compound, {(C(5)H(14)N(2))[BiCl(5)]}(n), the Bi(III) cation is coordinated by six Cl(-) anions in a distorted octa-hedral geometry. Two Cl(-) anions bridge neighboring Bi(III) cations, forming a zigzag polymeric chain along the a axis. The discrete methylpiperazinediium cation adopts a normal chair conformation and is linked to the polymeric chains by N-H⋯Cl hydrogen bonding.
منابع مشابه
Bis[(2S,4S)-4-(2-hydroxyethyl)-2-methylpiperazine-1,4-diium] di-μ-chlorido-bis[trichloridocadmium(II)]
The asymmetric unit of the title compound, (C(7)H(18)N(2)O)(2)[Cd(2)Cl(8)], comprises one 4-(2-hy-droxy-eth-yl)-2-methyl-piperazine-1,4-diium dication and a half [Cd(2)Cl(8)](4-) anion. The two Cd atoms are each coordinated by two bridging Cl atoms and three terminal Cl atoms and the [Cd(2)Cl(8)](4-) anion is located on an inversion centre. The crystal structure consists of N-H⋯Cl hydrogen-bond...
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