Synthesis of benzimidazoles via iridium-catalyzed acceptorless dehydrogenative coupling.

نویسندگان

  • Xiang Sun
  • Xiao-Hui Lv
  • Lin-Miao Ye
  • Yu Hu
  • Yan-Yan Chen
  • Xue-Jing Zhang
  • Ming Yan
چکیده

Iridium-catalyzed acceptorless dehydrogenative coupling of tertiary amines and arylamines has been developed. A number of benzimidazoles were prepared in good yields. An iridium-mediated C-H activation mechanism is suggested. This finding represents a novel strategy for the synthesis of benzimidazoles.

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عنوان ژورنال:
  • Organic & biomolecular chemistry

دوره 13 27  شماره 

صفحات  -

تاریخ انتشار 2015