Facile template-free synthesis of pine needle-like Pd micro/nano-leaves and their associated electro-catalytic activities toward oxidation of formic acid

نویسندگان

  • Rong Zhou
  • Weiqiang Zhou
  • Hongmei Zhang
  • Yukou Du
  • Ping Yang
  • Chuanyi Wang
  • Jingkun Xu
چکیده

Pine needle-like Pd micro/nano-leaves have been synthesized by a facile, template-free electrochemical method. As-synthesized Pd micro/nano-leaves were directly electrodeposited on an indium tin oxide substrate in the presence of 1.0 mM H2PdCl4 + 0.33 M H3PO4. The formation processes of Pd micro/nano-leaves were revealed by scanning electron microscope, and further characterized by X-ray diffraction and electrochemical analysis. Compared to conventional Pd nanoparticles, as-prepared Pd micro/nano-leaves exhibit superior electrocatalytic activities for the formic acid oxidation.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Role of gel aging in template-free synthesis of micro and nano-crystalline sodalites

A  facile  effective  stirring  aging  at  room  temperature  prior  to  conventional  hydrothermal treatment was employed in the template-free synthesis of micro- and nano-crystalline sodalites with  two  different  initial  gel  compositions.  The  effect  of  initial  Si/Al  molar  ratio,  NaOH concentration and stirring aging time were investigated on the morphology and particle size of the...

متن کامل

Facile one-pot surfactant-free synthesis of uniform Pd6Co nanocrystals on 3D graphene as an efficient electrocatalyst toward formic acid oxidation.

Ultrasmall and uniform Pd6Co nanocrystals were deposited on 3D graphene by a facile one-pot surfactant-free route for a catalyst toward formic acid oxidation, showing a much higher electrocatalytic activity, larger peak current density and better stability than Pd/3DG, Pd/C as well as commercial Pd-C, and thus offering great potential for an efficient anode catalyst toward high performance dire...

متن کامل

Facile synthesis of palladium right bipyramids and their use as seeds for overgrowth and as catalysts for formic acid oxidation.

Controlling the shape and thus facets of metal nanocrystals is an effective way to enhance their performance in catalytic reactions. While Pd nanocrystals with a myriad of shapes have been successfully prepared with good uniformity and in high yield, Pd right bipyramids (RBPs) that have a singly twinned structure have been elusive. We report a facile route based on polyol reduction for the synt...

متن کامل

Ag/Pt Core-Shell Nanoparticles on Graphene Nanocomposite for Effective Anodic Fuels Electro-oxidation

The nanocomposite consists of the Ag as a core and Pt as shell on the surface of graphene nanosheets (Ag/Pt-G) was synthesized with a simple method and used as a novel electrochemical platform for an efficient catalyst for oxidation of the ethanol, methanol and formic acid. The morphology and electrochemical properties of Ag/Pt-G nanocomposite were investigated by TEM, X-ray diffraction, and vo...

متن کامل

Facile synthesis of ultrathin single-crystalline palladium nanowires with enhanced electrocatalytic activities.

Ultrathin single-crystalline palladium nanowires (PdNWs) were rapidly prepared using a facile one-step soft-template-directed method. The utilization of dioctadecyldimethylammonium chloride and an appropriate crystallization temperature determined the construction of PdNWs together. The obtained PdNWs exhibited good electrocatalytic performance toward formic acid oxidation.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 6  شماره 

صفحات  -

تاریخ انتشار 2011