Modeling phase transition and metastable phases

نویسندگان

  • François James
  • Hélène Mathis
چکیده

We propose a model that describes phase transition including metastable phases present in the van der Waals Equation of State (EoS). We introduce a dynamical system that is able to depict the mass transfer between two phases, for which equilibrium states are both metastable and stable states, including mixtures. The dynamical system is then used as a relaxation source term in a isothermal two-phase model. We use a Finite volume scheme (FV) that treats the convective part and the source term in a fractional step way. Numerical results illustrate the ability of the model to capture phase transition and metastable states.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Formation of metastable phases by spinodal decomposition

Metastable phases may be spontaneously formed from other metastable phases through nucleation. Here we demonstrate the spontaneous formation of a metastable phase from an unstable equilibrium by spinodal decomposition, which leads to a transient coexistence of stable and metastable phases. This phenomenon is generic within the recently introduced scenario of the landscape-inversion phase transi...

متن کامل

کلراسیون زیرکونیای آسیابکاری شده

The effects of mechanochemical treatment of monoclinic zirconia in high energy planetary ball mill on its phase transformation were investigated. The mechanical treatment in ball mill reduces the grain size, increases microstrain, and causes phase transition to metastable nanostructured tetragonal and cubic phases. XRD and TEM results show considerable amounts of amorphous phase during ball mil...

متن کامل

The Stability of Al11Sm3 (Al4Sm) Phases in the Al-Sm Binary System

The relative stability of Al11Sm3 (Al4Sm) intermetallic phases was experimentally investigated through a series of heat treatments followed by microstructural, microchemical, and X-ray diffraction (XRD) analyses. The principal findings are that the high-temperature tetragonal phase is stable from 1655 to 1333 K and that the low-temperature orthorhombic phases, α and γ, have no range of full sta...

متن کامل

Calculation of minor hysteresis loops under metastable to stable transformations in vortex matter

We present a model in which metastable supercooled phase and stable equilibrium phase of vortex matter coexist in different regions of a sample. Minor hysteresis loops are calculated with the simple assumption of the two phases of vortex matter having field-independent critical current densities. We use our earlier published ideas that the free energy barrier separating the metastable and stabl...

متن کامل

Phase Polymorphism of [Cd(DMSO)6](ClO4)2 Studied by Differential Scanning Calorimetry

Five phase transitions of [Cd(DMSO)6](ClO4)2 have been detected by differential scanning calorimetry, namely the three reversible transitions: stable KIa ↔ stable KIb at TC4 = 242 K, due to a change of the crystal structure, metastable KII ↔ metastable KIII at TC3 = 318 K, and metastable KII ↔ overcooled K0 at TC2 = 347 K, one irreversible transition: KIa → K0 at TC1 = 376 K, and melting at Tt ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2016