Preparation of macroporous SnO2 films using PMMA microspheres and their sensing properties to NOx and H2

نویسندگان

  • Takeo Hyodo
  • Kazuhiro Sasahara
  • Yasuhiro Shimizu
  • Makoto Egashira
چکیده

Macroporous SnO2 (mp-SnO2(P-n); P means polymethylmethacrylate (PMMA) and n = diameter of PMMA microsphere) thick film gas sensors were fabricated by a modified sol-gel method by employing PMMA microspheres (n = 800, 400, 250 and 150 nm) as a template and SnCl2 as a tin source. Morphology of mp-SnO2 films was markedly dependent on the SnCl2 concentration and the diameter of PMMA microspheres. Especially, the ratio of the thickness of the SnO2 wall to the diameter of the hollow SnO2 microsphere seems to increase with decreasing the diameter of PMMA microspheres used.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Preparation of Mesoporous and/or Macroporous SnO2-Based Powders and Their Gas-Sensing Properties as Thick Film Sensors

Mesoporous and/or macroporous SnO(2)-based powders have been prepared and their gas-sensing properties as thick film sensors towards H(2) and NO(2) have been investigated. The mesopores and macropores of various SnO(2)-based powders were controlled by self-assembly of sodium bis(2-ethylhexyl)sulfosuccinate and polymethyl-methacrylate (PMMA) microspheres (ca. 800 nm in diameter), respectively. T...

متن کامل

Synthesis of Structured Macroporous TiO2 Thin Films and Investigation on Their Photocatalytic Activities

Synthesis of structured macroporous TiO2 thin films on quartz substrate (macroTiO2/Q) was performed by a dip-coating method using poly(methyl methacrylate) (PMMA) microspheres as template. Obtained TiO2 thin films kept high transparency and had anatase crystalline structure. SEM observations revealed that the macropores were uniformly formed on the film surface. The size of macropores was quite...

متن کامل

Improving Gas Sensing Properties of Tin Oxide Nanowires Palladium-Coated Using a Low Cost Technique

Thin films of SnO2 nanowires were successfully prepared by using chemical vapor deposition (CVD) process on quartz substrates. Afterwards, a thin  layer of palladium (Pd) as a catalyst was coated on top of nanowires. For the deposition of Pd, a simple and low cost technique of spray pyrolysis was employed, which caused an intensive enhancement on the sensing response of fabricated sensors...

متن کامل

Facile Synthesis and Acetone Sensing Performance of Hierarchical SnO2 Hollow Microspheres with Controllable Size and Shell Thickness

A facile method to prepare SnO2 hollow microspheres has been developed by using SiO2 microspheres as template and Na2SnO3 as tin resource. The obtained SnO2 hollow microspheres were characterized by X-ray diffraction, scanning electron microscopy, high resolution and transmission electron microscopy, and Brunauer−Emmett−Teller analysis, and their sensing performance was also investigated. It wa...

متن کامل

Influence of N2- and Ar-ambient annealing on the physical properties of SnO2: Co transparent conducting films prepared by spray pyrolysis technique

In this contribution, the Co doped SnO2 transparent semi-conducting films are prepared by spray pyrolysis technique and the influence of N2-and Ar-ambient annealing on their structural, electrical and optical properties are studied. The SnO2:Co thin films were deposited on the glass substrate at substrate temperature of 480 ˚C using an aqueous-ethanol solution consisting of tin and cobalt chlor...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2005