One-dimensional Hydrogen-bonded Chloride-Hydrate Assembly {[(H2O)4Cl2]}∞
نویسندگان
چکیده
A hydrogen-bonded chloride-hydrate assembly {[(H2O)4Cl2]2−}∞ has been ion-countered by the complex cations [Fe([9]aneS3)2] ([9]aneS3 = 1,4,7-trithiacyclononane). In {[(H2O)4Cl2]2−}∞, four water molecules and two chloride ions are self-assembled to form a one-dimensional supramolecular array of O–H· · ·O and O–H· · ·Cl hydrogen bonding, which consists of fused fourand six-membered rings. The discrete cation [Fe([9]aneS3)2] has a nearly regular octahedral FeS6 core with an average Fe–S bond length of 2.2586(5) Å.
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