An orthorhombic polymorph of 1-benzyl-1H-benzimidazole
نویسندگان
چکیده
The title compound, C(14)H(12)N(2), in contrast to the previously reported monoclinic polymorph [Lei et al. (2009 ▶). Acta Cryst. E65, o2613], crystallizes in the ortho-rhom-bic crystal system. The dihedral angle between the imidazole ring system and the phenyl ring is 76.78 (16)°. Weak C-H⋯N and C-H⋯π inter-actions are observed in the crystal structure.
منابع مشابه
Orthorhombic polymorph of 4-[(1H-benzimidazol-1-yl)methyl]benzoic acid
We reported recently the first polymorph of the title compound [Kuai & Cheng (2011a ▶). Acta Cryst., E67, o2787]. A second polymorph of the title compound, C(15)H(12)N(2)O(2), was unexpectedly obtained by the hydro-thermal reaction of the title compound with manganese chloride in the presence of potassium hydroxide at 413 K. The benzimidazole ring system is almost planar, with a maximum deviati...
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