Synthetic and catalytic intermediates in a magnesium promoted Tishchenko reaction.
نویسندگان
چکیده
Magnesium-aryloxide and -amide compounds supported by amidinate ligands are accessible in two-steps from a suitable Grignard reagent. Both species are active for the dimerization of benzaldehyde. The slower initiation by the aryloxide was exploited in the isolation of a bis-mesitylaldehyde adduct.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 41 36 شماره
صفحات -
تاریخ انتشار 2012