Detection of foreign phases in doped a-alumina powders by thermoluminescence
نویسندگان
چکیده
The thermoluminescence (TL) after excitation by UV or X-rays radiation of doped α-alumina powders is investigated. In the case of zirconia, the alumina-zirconia composites present five of the characteristic peaks of zirconia at –170, –145, –90, 0 and 95°C. After a thermal treatment of mixed oxides, a new peak is observed at –35°C in TL. This peak reveals the presence of stabilized tetragonal zirconia in the material. In the case of calcium, the TL curves of α-alumina doped by calcium present a double peak around 110 and 130°C which can be attributed to the presence of the hibonite phase: CaAl12O19. Moreover, in the case of zirconia, by comparing this analysis with those realised by X-rays diffraction (XRD), it can be shown that the TL has one better limit of detection than the XRD.
منابع مشابه
Detection of tetragonal zirconia in alumina–zirconia powders by thermoluminescence
The thermoluminescence (TL) after excitation by UV or X-rays radiation of alumina-zirconia powders is investigated. The composites present five of the characteristic peaks of zirconia at −170, −145, −90, 0 and 95 °C. After a thermal treatment of mixed oxides, a new peak is observed at −35 °C in TL. This peak reveals the presence of stabilized tetragonal zirconia in the material. Moreover by com...
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