Triphenyl[(triphenylphosphoranylidene)amino]phosphonium tetrakis(pentafluorophenyl)borate
نویسندگان
چکیده
In the title molecular salt, C36H30NP2(+)·C24BF20(-), the P-N bond lengths in the cation are equal [1.573 (2) and 1.572 (2) Å], indicating a resonance structure and the P-N-P bond angle is 144.79 (12)°. In the crystal, weak C-H⋯F interactions link the cations and the anions.
منابع مشابه
Tetrakis(triphenylphosphane-κP)silver(I) tetrafluoridoborate
The title complex, [Ag(C(18)H(15)P)(4)]BF(4), was prepared by the reaction of silver(I) tetra-fluorido-borate and triphenyl-phosphane in the presence of 1,2-bis-(pyridin-2-yl)ethyl-ene. The Ag(I) atom is tetra-hedrally coordinated by four P atoms from triphenyl-phosphane (PPh(3)) ligands. Due to symmetry, the tetra-fluorido-borate anion is disordered over three positions (each with one third oc...
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