2-Isopropyl-5-methyl­cyclo­hexyl N-cyclo­hexyl-P-phenyl­phospho­namidate

نویسندگان

  • Fan-Jie Meng
  • Hao Xu
  • Li-Juan Liu
  • Daqi Wang
  • Chang-Qiu Zhao
چکیده

The title compound, C(22)H(36)NO(2)P, features a P atom bonded to a phenyl ring, a cyclo-hexyl-amine unit and the O atom of a menthyl group. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds connect mol-ecules into a one-dimensional chain in the b direction.

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منابع مشابه

N-tert-Butyl O-2-isopropyl-5-methyl­cyclo­hexyl phenyl­phospho­namidate

In the title compound, C(20)H(34)NO(2)P, the P atom has an irregular tetra-hedral environment and exhibits S(p) chirality. In the crystal, weak inter-molecular N-H⋯O and C-H⋯O hydrogen bonds link the mol-ecules into chains extending in [010].

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2-Isopropyl-5-methyl­cyclo­hexyl diphenyl­phospho­namidate

In the title compound, C(22)H(30)NO(2)P, the P atom has an irregular tetra-hedral geometry. In the crystal, mol-ecules are connected by N-H⋯O hydrogen-bonding inter-actions, giving rise to a chain along the b axis. The phenyl ring of the anilino group is twisted by 77.40 (16)° relative to the other phenyl ring. The absolute configuration of phospho-rus is S(p).

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(R p)-2-Isopropyl-5-methyl­cyclo­hexyl isoprop­yl(phen­yl)phosphinate

The title compound, C(19)H(31)O(2)P, features a distorted tetra-hedral P atom that bonds to the phenyl ring, isopropyl and 2-isopropyl-5-methyl-cyclo-hexyl groups, and is determined as having an R(p) configuration. A chair conformation is observed for the cyclo-hexyl ring. In the crystal, mol-ecules are linked into chains running along the a axis by weak inter-molecular C-H⋯O hodrogen bonds.

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2-Isopropyl-5-methyl­cyclo­hexyl cyclo­hex­yl(phen­yl)phosphinate

In the title mol-ecule, C(22)H(35)O(2)P, the two cyclo-hexyl rings exhibit chair conformations. In the crystal, mol-ecules related by translation along the b axis are linked by the weak inter-molecular C-H⋯O hydrogen bonds.

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عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010