4-(2-Hydroxyethyl)anilinium 3-carboxy-4-hydroxybenzenesulfonate monohydrate
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چکیده
In the structure of the title compound, C(8)H(12)NO(+)·C(7)H(5)O(6)S(-)·H(2)O, isolated from the reaction of 2-(4-amino-phen-yl)ethanol with 5-sulfosalicylic acid, the cations form head-to-tail hydrogen-bonded chains through C(1) (1)(9) anilinium N(+)-H⋯O(hydrox-yl) inter-actions while the anions also form parallel but C(1) (1)(8)-linked chains through carboxylic acid O-H⋯O(sulfonate) inter-actions. These chains inter-associate through a number of N(+)-H⋯O and O-H⋯O bridging inter-actions, giving a two-dimensional array in the ab plane.
منابع مشابه
1-Hydroxyethyl-2-methyl-5-nitroimidazolium 3-carboxy-4-hydroxybenzenesulfonate
Cocrystallization of 1-hydroxy-ethyl-2-methyl-5-nitroimidazole (metronidazole) and 5-sulfosalicylic acid (5-H(2)SSA) from methanol solution yields the title salt, C(6)H(10)N(3)O(3) (+)·C(7)H(5)O(6)S(-). In the crystal structure, the ions are linked by a combination of inter-molecular O-H⋯O, N-H⋯O and C-H⋯O hydrogen bonds, forming a three-dimensional framework. The hydroxyl group of the cation i...
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The asymmetric unit of the title compound, C(5)H(12)N(+)·C(7)H(5)O(6)S(-)·H(2)O, contains a piperidinium cation, one 3-carb-oxy-4-hydroxy-benzene-sulfonate anion and one water mol-ecule. Inter-molecular O-H⋯O, O-H⋯S and N-H⋯O hydrogen bonds generate a three-dimensional hydrogen-bonded framework.
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Co-crystallization of 4,4'-methyl-enediphenyl-amine (MDA) and 5-sulfosalicylic acid (5-H(2)SSA) yields the title salt, C(13)H(16)N(2) (2+)·2C(7)H(5)O(6)S(-)·H(2)O. The asymmetric unit is comprised of one dication, two anions and one water mol-ecule. In the crystal structure, the components of the salt are linked by a combination of inter-molecular O-H⋯O, N-H⋯O and weak C-H⋯O hydrogen bonds into...
متن کامل4-(2-Hydroxyethyl)anilinium 3,5-dinitrobenzoate
In the title compound, C(8)H(12)NO(+)·C(7)H(3)N(2)O(6) (-), the anilinium and hydroxyl protons of the cation result in N-H⋯O, N-H⋯(O,O) and O-H⋯O hydrogen-bonding inter-actions with carboxyl-ate O-atom acceptors, forming a two-dimensional network structure. An intermolecular C-H⋯O interaction is also present.
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In the crystal structure of the title compound, C(9)H(7)N(2)O(2)S(+)·C(7)H(5)O(6)S(-)·2H(2)O, an H atom from the 5-sulfosalicylic acid is transferred to the pyridyl N atom, forming a salt. The dihedral angle between the thiazole and pyridinium rings is 5.909 (5)°. The crystal packing is determined by O-H⋯O and N-H⋯O hydrogen bonds involving water mol-ecules.
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