Effect of water on the ionothermal synthesis of molecular sieves.

نویسندگان

  • Huaijun Ma
  • Zhijian Tian
  • Renshun Xu
  • Bingchun Wang
  • Ying Wei
  • Lei Wang
  • Yunpeng Xu
  • Weiping Zhang
  • Liwu Lin
چکیده

AlPO4-11 and AlPO4-5 molecular sieves are ionothermally prepared without addition of water by using anhydrous starting materials, such as NH4H2PO4, pseudoboehmite (AlOOH), and NH4F. The synthesis appears to be an autocatalytic process. Water has a remarkable effect on the synthesis process. Addition of reagent quantities of water (H2O/Al = 1, molar ratio) can enhance the crystallization kinetics greatly.

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عنوان ژورنال:
  • Journal of the American Chemical Society

دوره 130 26  شماره 

صفحات  -

تاریخ انتشار 2008