Effect of water on the ionothermal synthesis of molecular sieves.
نویسندگان
چکیده
AlPO4-11 and AlPO4-5 molecular sieves are ionothermally prepared without addition of water by using anhydrous starting materials, such as NH4H2PO4, pseudoboehmite (AlOOH), and NH4F. The synthesis appears to be an autocatalytic process. Water has a remarkable effect on the synthesis process. Addition of reagent quantities of water (H2O/Al = 1, molar ratio) can enhance the crystallization kinetics greatly.
منابع مشابه
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 130 26 شماره
صفحات -
تاریخ انتشار 2008