3-(4-Methoxybenzylidene)-1,5-dioxaspiro[5.5]undecane-2,4-dione
نویسندگان
چکیده
In the title mol-ecule, C(17)H(18)O(5), which was prepared by the reaction of (R)-1,5-dioxaspiro-[5.5]undecane-2,4-dione and 4-meth-oxy-benzaldehyde with ethanol, the 1,3-dioxane ring is in a distorted envelope conformation with the spiro C atom forming the flap. The crystal structure is stabilized by weak inter-molecular C-H⋯O hydrogen bonds.
منابع مشابه
3-(4-Fluorobenzylidene)-1,5-dioxaspiro[5.5]undecane-2,4-dione
In the title mol-ecule, C(16)H(15)FO(4), the fused 1,3-dioxane and cyclo-hexane rings exhibit a bath and a chair conformation, respectively. In the crystal, weak inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into centrosymmetric dimers.
متن کامل3-(2,4-Dichlorobenzylidene)-1,5-dioxaspiro[5.5]undecane-2,4-dione
In the title mol-ecule, C(16)H(14)Cl(2)O(4), the 1,3-dioxane and cyclo-hexane rings exhibit distorted boat and chair conformations, respectively. In the crystal, a pair of weak inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into an inversion dimer.
متن کامل(Z)-3-(3-Phenylallylidene)-1,5-dioxaspiro[5.5]undecane-2,4-dione
In the title compound, C(18)H(18)O(4), the 1,3-dioxane ring adopts a distorted envelope conformation with the C atom common to the cyclo-hexane ring forming the flap. In the crystal, inversion dimers linked by pairs of C-H⋯O hydrogen bonds occur.
متن کامل3-(4-Bromobenzylidene)-1,5-dioxaspiro[5.5]undecane-2,4-dione
The title mol-ecule, C(16)H(15)BrO(4), was prepared by the reaction of (R)-2,4-dioxo-1,5-dioxaspiro-[5.5]undecane and 4-bromo-benzaldehyde with ethanol. The 1,3-dioxane ring exhibits a distorted boat and the fused cyclo-hexane ring exhibits a chair conformation.
متن کامل3-[(5-Methylfuran-2-yl)methylene]-1,5-dioxaspiro[5.5]undecane-2,4-dione
There are two crystallographically independent mol-ecules in the asymmetric unit of the title compound, C(15)H(16)O(5). In each, the 1,3-dioxane ring is in an envelope conformation with the C atom common to the cyclo-hexane ring forming the flap. The dihedral angles between the five essentially planar [maximum deviations from the least-squares planes of 0.049 (3) and 0.042 (3) Å] atoms of the 1...
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