INFLUENCE OF ADHESION AT STEEL/MORTAR INTERFACE ON CORROSION CHARACTERISTICS OF REINFORCING STEEL By

The mechanism of corrosion of reinforcing steel in concrete is discussed based on electrochemical and electron microscopy observations. The importance of calcium hydroxide precipitation on the steel surf ace in the steel/mortar interface is evaluated by placing filter paper around reinforcing steel bar specimens prior to casting in mortar, thus preventing direct contact between steel and mortar. The voids created presumably prevent calcium hydroxide crystals from forming on the steel surface. Specimens with filter paper are compared to specimens with good steel/mortar adhesion using rapid macrocell and corrosion potential tests and a scanning electron microscope (SEM) equipped with an energy dispersive spectrometer (EDS). The study included 21 macrocell and 16 corrosion potential tests run for periods of 25 to 89 days. Seven specimens were subjected to SEM/EDS analysis. Electrochemical results are mixed due to the influence of crevice corrosion. but it is generally shown that better protection is provided for steel with good steel/mortar adhesion than with filter paper. The filter paper, indeed, prevents calcium hydroxide crystals from forming on the steel surface. Corrosion products on active specimens with good mortar cover are shown to grow preferentially in voids created by air bubbles trapped in the mortar. The protective mechanism of calcium hydroxide crystals is proposed to be due to pH buffering by the hydroxyl ions released when the crystals are dissolved, a fact that cannot be proven easily, since many other factors may contribute to the protection of steel in concrete.