2,2′-Dimethoxy-4,4′-[rel-(2R,3S)-2,3-di­methylbutane-1,4-diyl]diphenol

نویسندگان

  • Carmen L. Salinas-Salazar
  • María del Rayo Camacho-Corona
  • Sylvain Bernès
  • Noemi Waksman de Torres
چکیده

The title mol-ecule, C(20)H(26)O(4), commonly known as meso-dihydro-guaiaretic acid, is a naturally occurring lignan extracted from Larrea tridentata and other plants. The mol-ecule has a noncrystallographic inversion center situated at the midpoint of the central C-C bond, generating the meso stereoisomer. The central C-C-C-C alkyl chain displays an all-trans conformation, allowing an almost parallel arrangement of the benzene rings, which make a dihedral angle of 5.0 (3)°. Both hydr-oxy groups form weak O-H⋯O-H chains of hydrogen bonds along [100]. The resulting supra-molecular structure is an undulating plane parallel to (010).

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عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009