Design and synthesis of novel bis-annulated caged polycycles via ring-closing metathesis: pushpakenediol
نویسندگان
چکیده
Intricate caged molecular frameworks are assembled by an atom economical process via a Diels-Alder (DA) reaction, a Claisen rearrangement, a ring-closing metathesis (RCM) and an alkenyl Grignard addition. The introduction of olefinic moieties in the pentacycloundecane (PCUD) framework at appropriate positions followed by RCM led to the formation of novel heptacyclic cage systems.
منابع مشابه
Design and synthesis of fused polycycles via Diels–Alder reaction and ring-rearrangement metathesis as key steps
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