[2-(1-{2-[Azanidyl(ethylsulfanyl)methylidene-κN]hydrazin-1-ylidene-κN 1}ethyl)phenolato-κO](dimethyl sulfoxide-κO)dioxidomolybdenum(VI)
نویسندگان
چکیده
The Mo(VI) atom in the title complex, [Mo(C(11)H(13)N(3)OS)O(2)(C(2)H(6)OS)], is N,N',O-coordinated by the dianionic tridentate ligand, two mutually cis oxide O atoms and a dimethyl sulfoxide O atom, defining a distorted octa-hedral N(2)O(4) donor set. The most prominent feature of the crystal packing is the formation of inversion dimers via pairs of N-H⋯O hydrogen bonds and eight-membered {⋯HNMoO}(2) loops. The Schiff base ligand is disordered over two orientations of equal occupancy.
منابع مشابه
[2-(1-{2-[Azanidyl(ethylsulfanyl)methylidene-κN]hydrazin-1-ylidene-κN 1}ethyl)phenolato-κO](pyridine-κN)nickel(II)
The Ni(II) atom in the title complex, [Ni(C₁₁H₁₃N₃OS)(C₅H₅N)], exists within a square-planar N₃O donor set provided by N,N',O atoms of the dianionic tridentate ligand and a pyridine N atom. The maximum deviation from the ideal geometry is seen in the N-Ni-N five-membered chelate bite angle of 83.28 (12)°. The pyridine mol-ecule forms a dihedral angle of 44.43 (6)° with the N₃O donor set. Supra-...
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