Synthesis, structure, and photovoltaic property of a nanocrystalline 2H perovskite-type novel sensitizer (CH3CH2NH3)PbI3
نویسندگان
چکیده
A new nanocrystalline sensitizer with the chemical formula (CH3CH2NH3)PbI3 is synthesized by reacting ethylammonium iodide with lead iodide, and its crystal structure and photovoltaic property are investigated. X-ray diffraction analysis confirms orthorhombic crystal phase with a = 8.7419(2) Å, b = 8.14745(10) Å, and c = 30.3096(6) Å, which can be described as 2 H perovskite structure. Ultraviolet photoelectron spectroscopy and UV-visible spectroscopy determine the valence band position at 5.6 eV versus vacuum and the optical bandgap of ca. 2.2 eV. A spin coating of the CH3CH2NH3I and PbI2 mixed solution on a TiO2 film yields ca. 1.8-nm-diameter (CH3CH2NH3)PbI3 dots on the TiO2 surface. The (CH3CH2NH3)PbI3-sensitized solar cell with iodide-based redox electrolyte demonstrates the conversion efficiency of 2.4% under AM 1.5 G one sun (100 mW/cm2) illumination.
منابع مشابه
Red-to-Black Piezochromism in a Compressible Pb−I−SCN Layered Perovskite
M of controlling semiconductor bandgaps are of great importance in materials design. In particular, fabrication of layered heterostructures with controlled thickness and composition allows for the composite’s electronic structures to be modulated. In recent decades, 2D organic−inorganic perovskites have gained attention as self-assembling heterostructures, whose optoelectronic properties can be...
متن کاملA Bismuth-Halide Double Perovskite with Long Carrier Recombination Lifetime for Photovoltaic Applications.
Despite the remarkable rise in efficiencies of solar cells containing the lead-halide perovskite absorbers RPbX3 (R = organic cation; X = Br(-) or I(-)), the toxicity of lead remains a concern for the large-scale implementation of this technology. This has spurred the search for lead-free materials with similar optoelectronic properties. Here, we use the double-perovskite structure to incorpora...
متن کاملHigh-performance hole-extraction layer of sol-gel-processed NiO nanocrystals for inverted planar perovskite solar cells.
Hybrid organic/inorganic perovskite solar cells have been rapidly evolving with spectacular successes in both nanostructured and thin-film versions. Herein, we report the use of a simple sol-gel-processed NiO nanocrystal (NC) layer as the hole-transport layer in an inverted perovskite solar cell. The thin NiO NC film with a faceted and corrugated surface enabled the formation of a continuous an...
متن کاملSynthesis and Investigation of Photovoltaic Properties of New Organic Dye in Solar Cells Device
In this paper, we designed and synthesized free-metal dyes based on indoline. The proposed dyes were synthesized from phenothiazine as the starting material by standard reactions. The chemical structure of the synthesized dye was confirmed using FT-IR, 1HNMR and DSC techniques. Spectrophotometric measurements of the organic dyes in acetonitrile and on a TiO2 substrate ...
متن کاملCrystal Structure Formation of CH3NH3PbI3-xClx Perovskite
Inorganic-organic hydride perovskites bring the hope for fabricating low-cost and large-scale solar cells. At the beginning of the research, two open questions were raised: the hysteresis effect and the role of chloride. The presence of chloride significantly improves the crystallization and charge transfer property of the perovskite. However, though the long held debate over of the existence o...
متن کامل