Synthesis of highly enantiomerically enriched planar chiral ruthenium complexes via Pd-catalysed asymmetric hydrogenolysis.
نویسندگان
چکیده
Key elements in this communication are a very efficient microwave synthesis of [RuCp(naphthalene)][PF(6)], the precursor of [RuCp(CH(3)CN)(3)][PF(6)], and a Pd-catalysed asymmetric hydrogenolysis to afford planar chiral ruthenium complexes with high levels of enantioselectivity using a bulky chiral phosphoramidite ligand.
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ورودعنوان ژورنال:
- Chemical communications
دوره 35 شماره
صفحات -
تاریخ انتشار 2009