Morphology-Controlled Synthesis of Hematite Nanocrystals and Their Optical, Magnetic and Electrochemical Performance

A series of α-Fe₂O₃ nanocrystals (NCs) with fascinating morphologies, such as hollow nanoolives, nanotubes, nanospindles, and nanoplates, were prepared through a simple template-free hydrothermal synthesis process. The results showed that the morphologies could be easily controlled by SO₄2- and H₂PO₄-. Physical property analysis showed that the α-Fe₂O₃ NCs exhibited shape- and size-dependent ferromagnetic and optical behaviors. The absorption band peak of the α-Fe₂O₃ NCs could be tuned from 320 to 610 nm. Furthermore, when applied as electrode material for supercapacitor, the hollow olive-structure exhibited the highest capacitance (285.9 F·g-1) and an excellent long-term cycling stability (93% after 3000 cycles), indicating that it could serve as a candidate electrode material for a supercapacitor.