Di-μ-hydroxido-bis[dimethyl(thiocyanato-κN)tin(IV)]
نویسندگان
چکیده
The Sn(IV) atom in the centrosymmetric title complex, [Sn2(CH3)4(NCS)2(OH)2], adopts a distorted trigonal-bipyramidal coordination environment defined by two methyl C atoms and one bridging hydroxide group in the equatorial plane while the other bridging hydroxide group and the N atom of the thio-cyanate anion are in the apical >positions. The dinuclear species are linked through O-H⋯S and C-H⋯ S hydrogen-bonding inter-actions into a three-dimensional network.
منابع مشابه
Dimethyl(1,10-phenanthroline-κ2 N,N′)bis(thiocyanato-κN)tin(IV)
The Sn(IV) atom in the title compound, [Sn(CH3)2(NCS)2(C12H8N2)], is located on a twofold rotation axis in a distorted octa-hedral enviroment. The methyl groups are trans to each other [C-Sn-C = 175.7 (3)°], whereas the thio-cyanate groups are cis to each other.
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