N-(3,4-Dimethyl­phen­yl)-4-methyl­benzene­sulfonamide

نویسندگان

  • B. Thimme Gowda
  • Sabine Foro
  • P. G. Nirmala
  • Hiromitsu Terao
  • Hartmut Fuess
چکیده

In the crystal structure of the title compound, C(15)H(17)NO(2)S, the conformations of the N-C bond in the C-SO(2)-NH-C segment are trans and gauche, respectively, with respect to the S=O bonds. The mol-ecule is bent at the S atom with a C-SO(2)-NH-C torsion angle of -61.8 (2)°. Furthermore, the conformation of the N-H bond and the 3-methyl group in the aniline benzene ring are nearly anti to each other. The dihedral angle between the benzene rings is 47.8 (1)°. In the crystal, N-H⋯O hydrogen bonds link the molecules into chains.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

4-Chloro-N-(3,4-dimethyl­phen­yl)-2-methyl­benzene­sulfonamide

In the title compound, C(15)H(16)ClNO(2)S, the conformation of the N-C bond in the C-SO(2)-NH-C segment is gauche with respect to the S=O bonds. Further, the N-H bond in the C-SO(2)-NH-C segment is syn with respect to the meta-methyl group in the aniline benzene ring and the ortho-methyl group in the sulfonyl benzene ring. The C-SO(2)-NH-C torsion angle is -49.72 (18)°. The sulfonyl and aniline...

متن کامل

N-(3,5-Dimethyl­phen­yl)-4-methyl­benzene­sulfonamide

In the title compound, C(15)H(17)NO(2)S, the dihedral angle between the two aromatic rings is 53.9 (1)°. The crystal structure features inversion-related dimers linked by N-H⋯O hydrogen bonds.

متن کامل

N-(2,3-Dimethyl­phen­yl)-4-methyl­benzene­sulfonamide

In the title compound, C(15)H(17)NO(2)S, the dihedral angle between the aromatic rings is 38.3 (1)°. The conformation of the N-H bond is anti to the methyl groups in the adjacent aromatic ring. In the crystal, N-H⋯O hydrogen bonds link the molecules into infinite chains.

متن کامل

N-(2,6-Dimethyl­phen­yl)-4-methyl­benzene­sulfonamide

In the title compound, C(15)H(17)NO(2)S, the mol-ecule is bent at the S atom, the C-SO(2)-NH-C torsion angle being 88.0 (2)°. The dihedral angle between the two aromatic rings is 49.8 (1)°. In the crystal, mol-ecules are linked into zigzag chains parallel to the a axis via N-H⋯O hydrogen bonds.

متن کامل

4-Chloro-N-(2,4-dimethyl­phen­yl)-2-methyl­benzene­sulfonamide

In the title compound, C(15)H(16)ClNO(2)S, the C-SO(2)-NH-C torsion angle is 67.45 (17)°. The two aromatic rings are tilted relative to each other by 44.5 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds..

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009