Comparative studies of gas chromatographic properties of new packings with chemically bonded complexes.

Specific interactions of aliphatic linear and branched hydrocarbons as well as cyclic and aromatic hydrocarbons with new packings containing chemically bonded complexes of transition metals are studied. The possibility of using these packings to separate these compounds is also discussed. The packings under study contain complexes of Cu(II) and Cr(III) chemically bonded to the silica surface. Chlorides of these metals are bonded to the silica surface by the use of the ketoimine group originally from 2-(3-triethoxysililpropylimino)-3-(n-buthyl)-pentanon-4. In order to determine an influence of the performed modification to gas chromatographic properties of the packings, such retention parameters as retention factor, retention index, molecular retention index, and specific retention volume are measured for these compounds. Based on the obtained values, a trial is taken to determine an influence of the nature of the bonded metal from the complex on the retention of the adsorbates under study and a dependence between a structure of an adsorbate molecule and values of charge-transfer interactions with the bonded metal complexes.