Metalloradical-catalyzed rearrangement of cycloheptatrienyl to benzyl.

نویسندگان

  • Yun Wai Chan
  • Kin Shing Chan
چکیده

Rh(ttp)(C(7)H(7)) rearranged to give Rh(ttp)(CH(2)Ph) quantitatively at 120 °C in 12 d (ttp = 5,10,15,20-tetratolylporphyrinato dianion). This process is 10(10) faster than for the organic analogue. Mechanistic investigation suggests that a Rh(II)(ttp)-catalyzed pathway is operating.

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عنوان ژورنال:
  • Chemical communications

دوره 47 16  شماره 

صفحات  -

تاریخ انتشار 2011