Transformable Single-Crystal Adsorbent Based on 1-D Coordination Polymer Skeletons
نویسندگان
چکیده
Recently, we found a single crystal host, [M(II)2(bza)4(pyz)]n (bza and pyz = benzoate and pyrazine, M = Rh and Cu), which is suitable for the study of gas-containing structure through gas adsorption. They generated gas inclusion crystals by transition from a closed to an open phase through the process of smooth physisorption; guest gases are adsorbed into the generated narrow channels of the lattice. I will present a new convenient procedure for crystallizing gas into a cosingle crystal state by putting the crystal adsorbent in a gaseous guest atmosphere, which is efficient to ascertain the exact molecular/atom structures with high resolution for included light aggregates.[1]
منابع مشابه
Synthesis and structural characterization of a single-crystal to single-crystal transformable coordination polymer.
A single-crystal to single-crystal transformable coordination polymer compound was hydrothermally synthesized. The structural rearrangement is induced by selecting a ligand that contains both strong and weaker coordinating groups. Both hydrated and dehydrated structures were determined by single crystal X-ray analysis.
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