(1-Acetylthiourea-κS)bromidobis(triphenylphosphane-κP)silver(I)
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چکیده
In the title complex, [AgBr(C3H6N2OS)(C18H15P)2], the Ag(I) ion is in a distorted tetra-hedral geometry coordinated by two P atoms from two triphenyl-phosphane ligands, one S atom of an acetyl-thio-urea ligand and one bromide ligand. There are intra-molecular N-H⋯Br and N-H⋯O hydrogen bonds present. In the crystal, pairs of N-H⋯S hydrogen bonds involving thio-urea groups form inversion dimers. In addition, moleclues pack to give sixfold phenyl embraces with an inter-molecular P⋯P distance of 6.4586 (17) Å.
منابع مشابه
Chlorido{4-ethyl-1-[1-(pyrazin-2-yl)ethylidene]thiosemicabazidato-κS}bis(triphenylphosphane-κP)silver(I)
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