Combination of a binaphthol-derived phosphite and a C1-symmetric phosphinamine generates heteroleptic catalysts in Rh- and Pd-mediated reactions.

نویسندگان

  • Luca Pignataro
  • Benita Lynikaite
  • Raffaele Colombo
  • Stefano Carboni
  • Martin Krupicka
  • Umberto Piarulli
  • Cesare Gennari
چکیده

Heteroleptic complexes, formed selectively by using a 1 : 1 combination of a sigma-donor and a pi-acceptor ligand, are involved in Rh- and Pd-catalysed reactions.

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عنوان ژورنال:
  • Chemical communications

دوره 24  شماره 

صفحات  -

تاریخ انتشار 2009