Photo- and thermally induced coloration of a crystalline MOF accompanying electron transfer and long-lived charge separation in a stable host-guest system.

نویسندگان

  • Yu Zeng
  • Zhiyong Fu
  • Hengjun Chen
  • Changchun Liu
  • Shijun Liao
  • Jingcao Dai
چکیده

A new type of electron transfer (ET) system was built via the combination of a highly stable MOF host framework and methyl viologen guest molecule. The π-stacking arrangements adjust the distance between the D-A components, contributing to the formation of an ultra long-lived charge separated state in the photo/thermo dual stimuli-responsive complex.

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عنوان ژورنال:
  • Chemical communications

دوره 48 65  شماره 

صفحات  -

تاریخ انتشار 2012