Crystal structure of a monoclinic polymorph of 5-amino-1,3,4-thia­diazol-2(3H)-one

نویسندگان

  • Namhun Kim
  • Sung Kwon Kang
چکیده

The title compound, C2H3N3OS, is a monoclinic (P21/c) polymorph of the previously reported triclinic structure [Kang et al. (2012 ▶). Acta Cryst. E68, o1198]. The asymmetric unit contains two independent mol-ecules which are essentially planar, with r.m.s. deviations of 0.001 and 0.032 Å from the mean plane defined by the seven non-H atoms. In the crystal, N-H⋯N and N-H⋯O hydrogen bonds link the mol-ecules into a sheet parallel to (111).

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5-Amino-1,3,4-thia­diazol-2(3H)-one

The asymmetric unit of the title compound, C(2)H(3)N(3)OS, contains three independent mol-ecules which are essentially planar, with r.m.s. deviations of 0.011 (2)-0.027 (2) Å from the mean plane defined by the seven non-H atoms. In the crystal, N-H⋯N and N-H⋯O hydrogen bonds link the mol-ecules into a sheet parallel to the (111) plane.

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عنوان ژورنال:

دوره 70  شماره 

صفحات  -

تاریخ انتشار 2014