Expanding the 2 , 2 ’ - bipyrimidine bridged 1 D homonuclear coordination polymers family : [ MIIbpymCl 2 ] ( M v Fe , Co ) magnetic and
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منابع مشابه
A family of cyanide-bridged molecular squares: structural and magnetic properties of [{MIICl2}2{CoII(triphos)(CN)2}2].xCH2Cl2, M = Mn, Fe, Co, Ni, Zn.
The syntheses, structures, and magnetic properties of a series of tetranuclear cyanide-bridged compounds are reported. This family of molecular squares, [{M(II)Cl2}2{Co(II)(triphos)(CN)2}2] (M = Mn ([CoMn]), Fe ([CoFe]), Co ([CoCo]), Ni ([CoNi]), and Zn ([CoZn]), triphos = 1,1,1-tris(diphenylphosphinomethyl)ethane), has been synthesized by the reaction of Co(II)(triphos)(CN)2 and MCl2 (M = Mn, ...
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The hydrothermal reaction of K(3)[Fe(CN)(6)], CuCl(2), and 2,2'-bipyridine (bipy) resulted in the formation of a 2D cyanide-bridged heterobimetallic Fe(II)-Cu(I) complex, [Fe(bipy)(2)(CN)(4)Cu(2)], 1. Working in the same conditions, but using 2,2'-bipyrimidine (bpym) instead of bipy and methanol as solvent, we obtained the homometallic Cu(I) complex [Cu(2)(CN)(2)(bpym)](2), 2. The structure of ...
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