Total Synthesis and Structural Revision of Antibiotic CJ-16,264.
نویسندگان
چکیده
The total synthesis and structural revision of antibiotic CJ-16,264 is described. Starting with citronellal, the quest for the target molecule featured a novel bis-transannular Diels-Alder reaction that casted stereoselectively the decalin system and included the synthesis of six isomers before demystification of its true structure.
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ورودعنوان ژورنال:
- Angewandte Chemie
دوره 54 32 شماره
صفحات -
تاریخ انتشار 2015