Preliminary assessment of perchlorate in ecological receptors at the Longhorn Army Ammunition Plant (LHAAP), Karnack, Texas.

نویسندگان

  • P N Smith
  • C W Theodorakis
  • T A Anderson
  • R J Kendall
چکیده

There have been increasing human health and ecological concerns about ionic perchlorate (ClO4-) since it was detected in drinking water sources in 1997. Perchlorate is known to affect thyroid function, causing subsequent hormone disruption and potential perturbations of metabolic activities. According to current estimates, perchlorate is found in the surface of groundwater of 14 states, including Texas. Longhorn Army Ammunition Plant, located in east central Texas, was a facility historically associated with perchlorate-containing propellants and rocket motors. Subsequently, perchlorate contamination in ground and surface waters at the facility has been reported. Soil, sediment, water, vegetation, and animal tissue samples were collected from several locations within the plant for a preliminary site assessment of perchlorate contamination. Perchlorate concentrations ranged from 555-5,557,000 ppb in vegetation, 811-2038 ppb in aquatic insects, below detection limits (ND) to 207 ppb in fish, ND-580 ppb in frogs, and ND-2328 ppb in mammals. Consistent with our hypothesis, aquatic organisms inhabiting perchlorate-contaminated surface water bodies contained detectable concentrations of perchlorate. Additionally, terrestrial organisms were exposed through pathways not necessarily related to contaminated surface waters. Therefore, these data demonstrate that aquatic and terrestrial species are exposed to perchlorate in the environment. To our knowledge, this represents the first incidence of perchlorate exposure among wild animals reported in the scientific literature.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Case Study of Ex-situ Biological Treatment of Perchlorate-contaminated Groundwater

Groundwater in certain areas at Longhorn Army Ammunition Plant (LHAAP) (Texas) contains volatile organic compounds (VOCs) and perchlorate from past operations at the site. Groundwater from a Burning Ground and Landfill is currently being remediated by pumping the water from an interceptor collection trench system to the surface, removing VOCs and metals in an ex-situ treatment process, and disc...

متن کامل

Rodent sperm analysis in field-based ecological risk assessment: pilot study at Ravenna army ammunition plant, Ravenna, Ohio.

Ecological risk assessment (ERA) guidance recommends that field-truthing efforts proceed when modeled hazard quotients (HQs) suggest that toxicological effects are occurring to site receptors. To date, no field methods have been proposed by the regulatory community that can lead to definitive determinations of acceptable or unacceptable risk for birds and mammals, the two terrestrial classes of...

متن کامل

ERDC/CERL TR-08-3, Anaerobic Treatment of Wastewaters Containing Perchlorate from Munitions Handling and Production

Perchlorate, an oxidizer routinely used in solid rocket motors, is easily washed out of old motors. The washout operation, however, leads to wastewater containing perchlorate. Royal Demolition Explosive (RDX), a major component of military high explosives, is transferred to Army industrial wastewaters during assembly of new munitions and during demilitarization of old munitions. New high explos...

متن کامل

Anaerobic treatment of army ammunition production wastewater containing perchlorate and RDX.

Perchlorate is an oxidizer that has been routinely used in solid rocket motors by the Department of Defense and National Aeronautics and Space Administration. Royal Demolition Explosive (RDX) is a major component of military high explosives and is used in a wide variety of munitions. Perchlorate bearing wastewater typically results from production of solid rocket motors, while RDX is transferre...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Ecotoxicology

دوره 10 5  شماره 

صفحات  -

تاریخ انتشار 2001