2-[2-(5-Bromothiophen-2-yl)-4,5-diphenyl-1H-imidazol-1-yl]-3-phenylpropan-1-ol
نویسندگان
چکیده
In the title compound, C28H23BrN2OS, the dihedral angles formed by the imidazole ring with the 5-bromo-thio-phenyl and phenyl rings are 76.90 (8), 34.02 (10) and 80.93 (11)°, respectively. The chiral centre maintains the S configuration of the l-phenyl-alaninol starting material. In the crystal, mol-ecules are linked by O-H⋯N hydrogen bonds, forming chains running parallel to the a-axis direction.
منابع مشابه
2-[4,5-Diphenyl-2-(pyridin-2-yl)-1H-imidazol-1-yl]-3-phenylpropan-1-ol
In the title compound, C(29)H(25)N(3)O, the central imidazole ring forms dihedral angles of 64.7 (3), 33.5 (3) and 81.2 (2)° with the pyridyl and two phenyl substituents, respectively. An intra-molecular C-H⋯N hydrogen bond is observed. In the crystal, O-H⋯N and C-H⋯O hydrogen bonds link the mol-ecules into chains parallel to the a axis.
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In the title compound, C(31)H(28)N(2)O, the dihedral angles formed by the imidazole ring with the three aryl substituents are 18.52 (8) and 85.56 (7) and 85.57 (7)°, respectively. In the crystal, mol-ecules are linked by O-H⋯N and C-H⋯O hydrogen bonds into chains parallel to the a axis.
متن کامل2-[2-(2-Nitrophenyl)-4,5-diphenyl-1H-imidazol-1-yl]-3-phenylpropan-1-ol
In the title compound, C30H25N3O3, the central imidazole ring forms dihedral angles of 77.34 (6), 12.56 (6) and 87.04 (6)°, respectively, with the o-nitro-benzene ring and the phenyl substituents in the 5- and 4-positions. The mol-ecular conformation is stabilized by weak intra-molecular C-H⋯π inter-actions. In the crystal, mol-ecules are linked by O-H⋯N hydrogen bonds, forming chains running p...
متن کامل3-(1H-Imidazol-1-yl)-1-phenylpropan-1-ol
In the title compound, C(12)H(14)N(2)O, the imidazole ring forms a dihedral angle of 66.73 (5)° with the phenyl ring. In the crystal, mol-ecules are linked via O-H⋯N and C-H⋯O hydrogen bonds into sheets lying parallel to (100). The crystal structure is further consolidated by C-H⋯π inter-actions.
متن کاملCrystal structure of 1-[2-(4-chlorophenyl)-4,5-diphenyl-1H-imidazol-1-yl]propan-2-ol
The title compound, C24H21ClN2O, crystallizes with two unique mol-ecules in the asymmetric unit. In each mol-ecule, the central imidazole ring is substituted at the 2-, 4- and 5-positions by benzene rings. The 2-substituted ring carries a Cl atom at the 4-position. One of the imidazole N atoms in each mol-ecule has a propan-2-ol substituent. In the crystal, a series of O-H⋯N, C-H⋯O and C-H⋯Cl h...
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