Discharge characteristics of silver vanadium oxide cathodes

نویسندگان

  • R. P. RAMASAMY
  • C. FEGER
  • T. STRANGE
چکیده

The discharge characteristics of silver vanadium oxide (SVO) as a cathode in lithium–silver vanadium oxide (Li–SVO) primary battery was studied under various operating conditions. The cathode yielded a capacity of 260 mAh g at a current density of 0.08 mA cm, although the theoretical capacity of this material is 315 mAh g. The pulse discharge characteristics were studied under conditions that simulate battery operation inside an implantable cardio-verter defibrillator (ICD). The variation of the ohmic resistance of the system was studied as a function of depth of discharge. Rate capability and impedance studies indicated high diffusion limitations for this system especially at high depth of discharge. Morphological changes during discharge were also discussed using scanning electron microscopic studies.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Vanadium Oxide Nanostructures for Lithium Battery Applications

Lithium and Lithium-ion batteries for portable electronic devices and hybrid electric vehicles have gained great importance for energy storage today. However, how to prepare cathode materials with higher energy density, high potentials, and longer cycle life is still a challenge. Compared with commercial LiCoO2, vanadium oxides have higher specific capacity and interesting layered structures, w...

متن کامل

Electrochemical intercalation of lithium into polypyrrole/silver vanadium oxide composite used for lithium primary batteries

Hybrid composites of polypyrrole (PPy) and silver vanadium oxide (SVO) used for lithium primary batteries were chemically synthesized by an xidative polymerization of pyrrole monomer on the SVO surface in an acidic medium. The composite electrode exhibited higher discharge capacity nd better rate capability as compared with the pristine SVO electrode. The improvement in electrochemical performa...

متن کامل

Bottom-up approach toward single-crystalline VO2-graphene ribbons as cathodes for ultrafast lithium storage.

Although lithium ion batteries have gained commercial success owing to their high energy density, they lack suitable electrodes capable of rapid charging and discharging to enable a high power density critical for broad applications. Here, we demonstrate a simple bottom-up approach toward single crystalline vanadium oxide (VO2) ribbons with graphene layers. The unique structure of VO2-graphene ...

متن کامل

Ag4V2O6F2: an electrochemically active and high silver density phase.

Low-temperature hydrothermal techniques were used to synthesize single crystals of Ag(4)V(2)O(6)F(2). This previously unreported oxide fluoride phase was characterized by single-crystal X-ray diffraction and IR spectroscopy and was also evaluated as a primary lithium battery cathode. Crystal data: monoclinic, space group P2(1)/n (No. 14), with a = 8.4034(4) A, b = 10.548(1) A, c = 12.459(1) A, ...

متن کامل

V2O5 NanoElectrodes with High Power and Energy Densities for Thin Film LiIon Batteries

Nanostructured V 2 O 5 thin fi lms have been prepared by means of cathodic deposition from an aqueous solution made from V 2 O 5 and H 2 O 2 directly on fl uorine-doped tin oxide coated (FTO) glasses followed by annealing at 500 ° C in air, and studied as fi lm electrodes for lithium ion batteries. XPS results show that the as-deposited fi lms contained 15% V 4 + , however after annealing all t...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2006