catena-Poly[[bromidocopper(I)]-μ-η2,σ1-3-(2-allyl-2H-tetra­zol-5-yl)pyridine]

نویسنده

  • Wei Wang
چکیده

The title compound, [CuBr(C(9)H(9)N(5))](n), has been prepared by the solvothermal treatment of CuBr with 3-(2-allyl-2H-tetra-zol-5-yl)pyridine. It is a new homometallic Cu(I) olefin coord-ination polymer in which the Cu(I) atoms are linked by the 3-(2-allyl-2H-tetra-zol-5-yl)pyridine ligands and bonded to one terminal Br atom each. The organic ligand acts as a bidentate ligand connecting two neighboring Cu centers through the N atom of the pyridine ring and the double bond of the allyl group. A three-dimensional structure is formed through weak Cu-Br [3.1579 (8) Å], C-H⋯Br and C-H⋯N inter-actions.

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عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008