Use of 95Mo NMR Spectroscopy as a New Approach to Structural Analysis of Diamagnetic Molybdenum Complexes
نویسندگان
چکیده
Molybdenum has been widely used as a redoxactive catalyst both in chemical systems and the living cell1 . Its catalytic versatility seems mainly due to the fact that it can be more or less readily stabilized in several different oxidation states ranging from 0 to + VI. Mononuclear and diamagnetic complexes have been isolated in the oxidation states 0, + IV and + VI, whereas paramagnetic species could be discovered by Electron Paramagnetic Resonance predominantly in the + V state 2. Three major results of preceding NMR study on 95Mo and
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