Cross-Linked CoMoO4/rGO Nanosheets as Oxygen Reduction Catalyst

نویسندگان

  • Jiaqi Fu
  • Jiang-Li Meng
  • Mei-Jie Wei
  • Hong-Ying Zang
  • Hua-Qiao Tan
  • Yong-Hui Wang
  • Haralampos N. Miras
  • Yang-Guang Li
چکیده

Development of inexpensive and robust electrocatalysts towards oxygen reduction reaction (ORR) is crucial for the cost-affordable manufacturing of metal-air batteries and fuel cells. Here we show that cross-linked CoMoO4 nanosheets and reduced graphene oxide (CoMoO4/rGO) can be integrated in a hybrid material under one-pot hydrothermal conditions, yielding a composite material with promising catalytic activity for oxygen reduction reaction (ORR). Cyclic voltammetry (CV) and linear sweep voltammetry (LSV) were used to investigate the efficiency of the fabricated CoMoO4/rGO catalyst towards ORR in alkaline conditions. The CoMoO4/rGO composite revealed the main reduction peak and onset potential centered at 0.78 and 0.89 V (vs. RHE), respectively. This study shows that the CoMoO4/rGO composite is a highly promising catalyst for the ORR under alkaline conditions, and potential noble metal replacement cathode in fuel cells and metal-air batteries.

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تاریخ انتشار 2017