Efficient Red-Emitting Electrophosphorescent Polymers
نویسندگان
چکیده
We report the synthesis and characterization of a series of electrophosphorescent polymers with a polyfluorene backbone, containing a red-emitting iridium complex and carrier-transporting units as the substitutes of the C-9 position of fluorene. Different specimens and contents of the hole-transporting moieties were found to influence the electroluminescent properties of the polymers. Incorporation of a hole-transporting/electron-blocking interfacial layer and utilization of an efficient electron injection cathode led to the saturated red-emitting electrophosphorescent polymer devices with the peak luminance efficiency and power conversion efficiency of 9.3 cd A and 10.5 lm W, respectively. The efficiencies were 8 cd A/8 lm W and 5.9 cd A/4.6 lm W, respectively, at 100 and 1000 cd m.
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