Spin-crossover behavior and electrical conduction property in iron(II) complexes with tetrathiafulvalene moieties.
نویسندگان
چکیده
Iron(II) complexes with neutral and oxidized tetrathiafulvalene (TTF) moieties were prepared and X-ray crystallographic analyses, magnetic and electrical resistivity measurements suggested an interaction of spin transition and electrical conductivity.
منابع مشابه
Thermal and near-infrared light induced spin crossover in a mononuclear iron(ii) complex with a tetrathiafulvalene-fused dipyridophenazine ligand.
A mononuclear Fe(ii) complex involving a tetrathiafulvalene-based ligand exhibits thermal spin-crossover (around 143 K) with pronounced hysteresis behaviour (48 K). The chromophoric and π-extended ligand allows Near-Infrared (NIR) sensitization for the light-induced excited spin-state trapping (LIESST) with T(LIESST) = 90 K.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 40 10 شماره
صفحات -
تاریخ انتشار 2011