New outcomes of Lewis base addition to diboranes(4): electronic effects override strong steric disincentives.
نویسندگان
چکیده
Two surprising new outcomes of the reaction of Lewis bases with dihalodiboranes(4) are presented, including sp(2)-sp(3) diboranes in which the Lewis base unit is bound to a highly sterically congested boron atom, and a rearranged double base adduct. The results provide a fuller understanding of the reactivity of diboranes, a poorly-understood class of molecule of critical importance to synthetic organic chemistry.
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ورودعنوان ژورنال:
- Chemical communications
دوره 52 27 شماره
صفحات -
تاریخ انتشار 2016