Poly[aquabis(μ4-naphthalene-1,4-dicarboxylato)(1,10-phenanthroline-5,6-dione)dimanganese(II)]
نویسندگان
چکیده
The three-dimensional coordination polymer, [Mn(2)(C(12)H(6)O(4))(2)(C(12)H(6)N(2)O(2))(H(2)O)](n), features a water-coord-inated Mn(II) ion and an N-heterocycle-chelated Mn(II) ion, both in six-coordinate octa-hedral geometries. Of the two rigid dianions, one is bonded to four Mn(II) ions, with each of the O atoms being connected to a different metal ion. The other dianion uses one carboxyl-ate group to chelate to one Mn(II) ion and its other carboxyl-ate group to bind to two Mn(II) ions.
منابع مشابه
Poly[diaqua(μ4-2,5-dicarboxybenzene-1,4-dicarboxylato-κ4 O 1:O 2:O 4:O 5)(μ2-2,5-dicarboxybenzene-1,4-dicarboxylato-κ2 O 1:O 4)bis(1,10-phenanthroline-κ2 N,N′)dimanganese(II)]
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