Synthesis and characterisation of 3,4-dialkoxy-substituted benzo-1,3,2-dithiazolyl radicals.

نویسندگان

  • Antonio Alberola
  • Dana Eisler
  • Robert J Less
  • Efren Navarro-Moratalla
  • Jeremy M Rawson
چکیده

The conversion of 3,4-dialkoxy-benzenes into dialkoxy-benzo-1,3,2-dithiazolyls is described and representative examples (1 and 2) derived from benzodioxole and veratrol, respectively, are reported. Whilst 1 is a dimeric pi*-pi* dimer, the dimethoxy derivative 2 is monomeric in the solid state and exhibits antiferromagnetic interactions.

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عنوان ژورنال:
  • Chemical communications

دوره 46 33  شماره 

صفحات  -

تاریخ انتشار 2010