phenylthiourea modified highly ordered nanoporous silica for heavy metal ion (hg2+ ) trapping
نویسندگان
چکیده
the phenylthiourea-substituted triethoxysilane as a silane agent was synthesized and grafted on highly ordered nanoporous silica (lus-1) with a textured morphology and hexagonal array. this material (tu-lus-1) contained 0.8 mmol/g of soft base phenylthiourea group and surface area 760 m2g-1 and was able to adsorb 0.75 mmolhg/g of tu-lus-1 in endothermic reaction.
منابع مشابه
Phenylthiourea Modified Highly Ordered Nanoporous Silica for Heavy Metal Ion (Hg2+ ) Trapping
The phenylthiourea-substituted triethoxysilane as a silane agent was synthesized and grafted on highly ordered nanoporous silica (LUS- 1) with a textured morphology and hexagonal array. This material (Tu-LUS-1) contained 0.8 mmol/g of soft base phenylthiourea group and surface area 760 m2 g-1 and was able to adsorb 0.75 mmolHg/g of TU-LUS-1 in endothermic reaction.
متن کاملModified SBA-15 mesoporous silica for heavy metal ions remediation.
N-Propylsalicylaldimino-functionalized SBA-15 mesoporous silica was prepared, characterized and used as an adsorbent for heavy metal ions. The organic-inorganic hybrid material was obtained using successive grafting procedures of SBA-15 silica with 3-aminopropyl-triethoxysilane and salicylaldehyde, respectively. For comparison an amorphous silica gel was functionalized using the same procedure....
متن کاملHighly efficient catalyst for removal of heavy metal ions modified by a novel Schiff base ligand
An alomina-based nano adsorbent was prepared by modification of the external surface of γ-alumina (γ-Al2O3) nanoparticles with functional groups of a new Schiff base 4-[(2-hydroxy-3-methoxy-benzylidene)-amino]-5-methyl-2,4-dihydro-[1,2.4]triazole-3-thione] “L”. In order to the removal of Cr(VI) from aqueous solutions, we used the reaction of the sodium dodecyl sulfate coated nano-alumina with L...
متن کاملPotentiometric detection of mercury(II) ions using a carbon paste electrode modified with substituted thiourea-functionalized highly ordered nanoporous silica.
A potentiometric sensor is reported for the mercury(II) detection, which uses substituted thiourea-functionalized nanoporous silica (FTU-LUS-1) as the sensitive material. Substituted thiourea (FTU) and FTU-LUS-1 were first prepared and then characterized by 1H NMR, 19F NMR, 13C NMR, FTIR, XRD, TG and CNS elemental analysis. The electrodes with FTU-LUS-1 proportion of 10.0 wt% demonstrated very ...
متن کاملDirect oxidation of benzene to phenol in liquid phase by H2O2 over vanadium catalyst supported on highly ordered nanoporous silica
Vanadium supported on highly ordered nanoporous silica (VOx-LUS-1) was synthesized and characterized by XRD, Nitrogen adsorption‑desorption isotherms and UV-visible spectrophotometer. Direct oxidation of benzene to phenol in liquid phase by H2O2 peroxide were examined by using various solvents (methanol, acetone, acetic acid, acetonitryl). The maximum yield (25%) and selectivity (73%) of the ph...
متن کاملSynthesis of new antibacterial composite coating for titanium based on highly ordered nanoporous silica and silver nanoparticles.
Infection is the most common factor that leads to dental titanium implant failure. Antibacterial implant surfaces based on nano-scale modifications of the titanium appear as an attractive strategy for control of peri-implantitis. In the present work, the preparation and antibacterial properties of a novel composite coating for titanium based on nanoporous silica and silver nanoparticles are pre...
متن کاملمنابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
journal of nanostructuresناشر: university of kashan
ISSN 2251-7871
دوره 2
شماره 1 2012
میزبانی شده توسط پلتفرم ابری doprax.com
copyright © 2015-2023