to control bead size distribution in suspension polymerization

Dynamic Evolution of Droplet/Particle Size Distribution in Suspension Polymerization of Styrene

Control of Particle Size Distribution in Emulsion Co-polymerization Processes

A mid-course correction (MCC) policy has been shown as a practical approach to compensate the effects of the new disturbances on the final particle size distribution (PSD) in the emulsion polymerization process. However, the development of control model remains immature in the practical sense. In this paper, a control strategy to control the bi-modal particle size distribution in an emulsion co...

Measurement of particle size distribution in suspension polymerization using in situ laser backscattering

Many methods have been developed for characterizing the particle size distribution (PSD) in a suspension polymerization reactor, but are restricted to suspensions with low volume fractions of polymer or to determining the PSD only at the end of the batch. Laser backscattering can be used to measure the chord length distribution for slurries with high particle densities. Here, a combination of i...

Microfluidic Bead Suspension Hopper

Many high-throughput analytical platforms, from next-generation DNA sequencing to drug discovery, rely on beads as carriers of molecular diversity. Microfluidic systems are ideally suited to handle and analyze such bead libraries with high precision and at minute volume scales; however, the challenge of introducing bead suspensions into devices before they sediment usually confounds microfluidi...

the effects of temperature, initiator and stabilizer on polymer particle size in suspension polymerization of styrene

in suspension polymerization, particle size distribution of polymer is the outcome of dynamic equilibrium between the break up and coalescence phenomena. the rates of break up and coalescence and consequently polymerization stability depend on several parameters, the most important of which are type and concentration of stabilizer. in this study, the effects of type and concentration of stabili...

Inferential MIMO predictive control of the particle size distribution in emulsion polymerization

A new inferential 2-step multiple input/multiple output (MIMO) model predictive control (MPC) of the particle size distribution (PSD) in emulsion polymerization processes is proposed. The bulk-like model describing the PSD is used with the material balances of initiator, radicals, monomer and surfactant. The inferential 2-step control strategy uses two measurements available online (without del...